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Browsing Article by Author "Sadler, Peter J."

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Effect of cysteine thiols on the catalytic and anticancer activity of Ru(ii) sulfonyl-ethylenediamine complexes

Chen, Feng; Romero-Canelón, Isolda; Habtemariam, Abraha; Song, Ji-Inn; Banerjee, Samya; Clarkson, Guy J.; Song, Lijiang; Prokes, Ivan; Sadler, Peter J. (Royal Society of Chemistry, 2022-02-28)

We have synthesized a series of novel substituted sulfonyl ethylenediamine (en) RuII arene complexes 1-8 of [(η6-arene)Ru(R1-SO2-EnBz)X], where the arene is benzene, HO(CH2)2O-phenyl or biphenyl (biph), X = Cl or I, and ...
Experimental and theoretical evidence for unprecedented strong interactions of gold atoms with boron on boron/sulfur-doped carbon surfaces

Banerjee, Samya; Wolny, Juliusz A.; Danaie, Mohsen; Barry, Nicolas P. E.; Han, Yisong; Amari, Houari; Beanland, Richard; Schünemann, Volker; Sadler, Peter J. (Royal Society of Chemistry, 2023-12-11)

The 16e square-planar bis-thiolato-Au(iii) complexes [AuIII(1,2-dicarba-closo-dodecarborane-1,2-dithiolato)2][NBu4] (Au-1) and [AuIII(4-methyl-1,2-benzenedithiolato)2][NBu4] (Au-2) have been synthesized and fully characterized. ...
Kinetics and mechanism of sequential ring methyl C-H activation in cyclopentadienyl rhodium(iii) complexes

Sink, Alexandra; Banerjee, Samya; Wolny, Juliusz A.; Imberti, Cinzia; Lant, Edward C.; Walker, Marc; Schünemann, Volker; Sadler, Peter J. (Royal Society of Chemistry, 2022-08)

We have studied activation of the methyl C-H bonds in the cyclopentadienyl ligands of half-sandwich Rh(iii) complexes [η5-CpXRh(N,N′)Cl]+ by observing the dependence of sequential H/D exchange on variations in CpX = Cp* ...

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