Urea–hydrogen peroxide prompted the selective and controlled oxidation of thioglycosides into sulfoxides and sulfones

dc.contributor.author	Singh, Adesh Kumar
dc.contributor.author	Tiwari, Varsha
dc.contributor.author	Kunj Bihari, Mishra
dc.contributor.author	Gupta, Surabhi
dc.contributor.author	Kandasamy, Jeyakumar
dc.date.accessioned	2019-10-23T06:39:54Z
dc.date.available	2019-10-23T06:39:54Z
dc.date.issued	2017-05-23
dc.identifier.issn	18605397
dc.identifier.uri	http://localhost:8080/xmlui/handle/123456789/415
dc.description.abstract	A practical method for the selective and controlled oxidation of thioglycosides to corresponding glycosyl sulfoxides and sulfones is reported using urea–hydrogen peroxide (UHP). A wide range of glycosyl sulfoxides are selectively achieved using 1.5 equiv of UHP at 60 °C while corresponding sulfones are achieved using 2.5 equiv of UHP at 80 °C in acetic acid. Remarkably, oxidation susceptible olefin functional groups were found to be stable during the oxidation of sulfide.	en_US
dc.language.iso	en	en_US
dc.publisher	Beilstein-Institut Zur Forderung der Chemischen Wissenschaften	en_US
dc.subject	monosaccharides; oxidation; sulfones; sulfoxides; thioglycosides; urea–hydrogen peroxide	en_US
dc.title	Urea–hydrogen peroxide prompted the selective and controlled oxidation of thioglycosides into sulfoxides and sulfones	en_US
dc.type	Article	en_US