Sink, Alexandra; Banerjee, Samya; Wolny, Juliusz A.; Imberti, Cinzia; Lant, Edward C.; Walker, Marc; Schünemann, Volker; Sadler, Peter J.
(Royal Society of Chemistry, 2022-08)
We have studied activation of the methyl C-H bonds in the cyclopentadienyl ligands of half-sandwich Rh(iii) complexes [η5-CpXRh(N,N′)Cl]+ by observing the dependence of sequential H/D exchange on variations in CpX = Cp* ...