Synthesis and computational aspects of Al(ii)-Al(ii) and Ga(ii)-Ga(ii) dihalides based on an amidinate scaffold

Kumar, Arun; Banerjee, Samya; Banerjee, Samya; Nazish, Mohd; Graw, Nico; Herbst-Irmer, Regine; Stalke, Dietmar; Lourderaj, Upakarasamy; Roesky, Herbert W.

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dc.contributor.author	Kumar, Arun
dc.contributor.author	Banerjee, Samya
dc.contributor.author	Banerjee, Samya
dc.contributor.author	Nazish, Mohd
dc.contributor.author	Graw, Nico
dc.contributor.author	Herbst-Irmer, Regine
dc.contributor.author	Stalke, Dietmar
dc.contributor.author	Lourderaj, Upakarasamy
dc.contributor.author	Roesky, Herbert W.
dc.date.accessioned	2023-04-24T05:49:41Z
dc.date.available	2023-04-24T05:49:41Z
dc.date.issued	2022-02-28
dc.identifier.issn	14779226
dc.identifier.uri	http://localhost:8080/xmlui/handle/123456789/2206
dc.description	This paper is submitted by the author of IIT (BHU), Varanasi	en_US
dc.description.abstract	Amidinate compounds with stabilized aluminium(ii) and gallium(ii) elements of composition L2M2X2 (3 and 4) have been prepared from their LMX2 (1 and 2) precursor, where M = Al (1 and 4) and Ga (2 and 3); L = PhC(NiPr2C6H3)2 (1 and 4) and PhC(NtBu)2 (2 and 3); and X is I (1 and 4) and Cl (2 and 3) and insights into their bonding are gained. The M-M bond lengths are reported along with the single-crystal X-ray structures of 1-4.	en_US
dc.description.sponsorship	HWR thanks the DFG for financial support (RO 224/71-1). NS and UL acknowledge NISER Bhubaneswar for the computational facility. UL also acknowledges the support from SERB, Department of Science and Technology (EMR/2017/004843).	en_US
dc.language.iso	en	en_US
dc.publisher	Royal Society of Chemistry	en_US
dc.relation.ispartofseries	Dalton Transactions;Volume 51, Issue 12, Pages 4898 - 4902
dc.subject	Aluminum compounds	en_US
dc.subject	Scaffolds	en_US
dc.subject	Single crystals	en_US
dc.subject	Amidinates	en_US
dc.subject	Computational aspects	en_US
dc.subject	Dihalides	en_US
dc.subject	Single crystal x-ray structures	en_US
dc.subject	Gallium compounds	en_US
dc.title	Synthesis and computational aspects of Al(ii)-Al(ii) and Ga(ii)-Ga(ii) dihalides based on an amidinate scaffold	en_US
dc.type	Article	en_US